
The agency plans to launch two scientific payloads from the airport this year after five failed attempts last year.
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The balloon was airborne around 11am, and may circle Earth for up to 100 days.
Such balloons have been making headlines, after the US shot down a suspected Chinese spy balloon in its airspace earlier this year.
The balloon will carry a Super Pressure Balloon Imaging Telescope, from Princeton University.
Nasa said the purpose of the launch is to further test and qualify the technology, which can offer cost savings compared to space missions.
Balloon programme office chief Debbie Fairbrother said a lot of different weather factors needed to line up, and so far, the forecast was favourable.

Wānaka Airport and the park alongside the airport will be closed to the public so anyone wanting to see the super pressure balloon is advised to head for higher ground.
The best viewing points will be on the hill on the Hāwea side of the Red Bridge by Kane Road or on the Hāwea Flat side of the Clutha River.
There will also be a live feed of the launch here.